Derivation of Van der Waals Equation With Simple Step By Step Explanation
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Express the van der Waals equation of state as a virial expansion in powers of 1 / Vm and obtain expressions for B and C in terms of the parameters a and b. The expansion you will need is (1-x)^-1=1 x x^2 ⋯Measurements on argon gave B=-21.7 cm^3 mol^-1 and C=1200 cm^6 mol^-2 for the virial coefficients at 273 K. What are the values of a and b in the corresponding van der Waals equation of state? | Numerade
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